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Ref:
https://goo.gl/search/reaction+between+benzene+and+chlorine

electrophilic substitution - the halogenation of benzene - Chemguide Benzene reacts with chlorine or bromine in an electrophilic substitution reaction, but only in the presence of a catalyst. ... It reacts with some of the chlorine or bromine to form iron(III) chloride, FeCl3, or iron(III) bromide, FeBr3.

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